If the library folders have been moved to the new computer then it is probably just a case of telling Calibre about them.
If you click on the 'Library' icon on the main toolbar you get the option to switch to a new library. You can browse to where the library folder is located; make sure that the option to use an existing library at that location is ticked and then open the library. That will add that as a new entry to the quick Switch list of libraries.
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