You might try 2epub.com. Not sure about Word, but I uploaded an OpenOffice doc and the conversion was pretty good. It even created a chapter point at a manual page break.
Other than that, creating using Calibre, I like to put each chapter into its own HTML and create an index that I import into Calibre. Then I just use ePubFixer to remove the HTML TOC. It requires some search and replace editing, but works exactly like I want.
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