Do a search and replace
Search for
(\s)"(\w)
(copy & paste a backward quote instead of the ")
Replace with
\1"\2
(copy & paste an open quote instead of the ")
That should do it, step through a few first, and only if you're happy - replace all.
Edit:
Do this on the converted epub, with the incorrect 'smartquotes'
Needless to say, make sure you have a backup
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