Q-Squared was the one I would recommend. Anything by Peter David is great.
Final Frontier was good, although it's contradicted now by the movie. Another good book was The Kobayashi Maru, which details how Kirk, Sulu, Checkov, and Scotty each deal with the test. (Scotty's solution is almost as creative as Kirk's!) (Also note that Kirk's solution is different from that shown in the latest movie.)
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