It is not clear from your description what the problem might be, but I suspect it is something to do with the way your web server is configured. You need to have your Calibre library folder visible from the web server, and the calibre2opds catalog folder needs to be a sub-folder of that. All book and catalog files must be accessible via the web server.
If you want to PM me the URL I could see if I can spot anything obvious.
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