Seconding many of the recommendations above, including Sharon Lee/Steven Miller and Linnea Sinclair (Accidental Goddess is amazing)
Lighter sci-fi romance:
Coffee Cup Dreams by J. A. Marlow
Dark Horse by Michelle Diener
Ruby Lionsdrake series
For not as light romantic science fiction:
Brainships series - by Anne McCaffery
Disappearing Act - by Margaret Ball
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