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Main question is, are your two calibre installations (PC & laptop) pointing at the same library? I.e. does your laptop calibre look at the library you originally created on your PC?
It is certainly possible to do this, but you must be careful to never have both calibre's running at the same time. If you can avoid that, there is no problem to having calibre installed in both places. That's actually my set up.
Also, some more details about what you have done, especially on the laptop, would be helpful for people here to help you out.
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