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In OpenOffice Writer, it's Format > Character > Spacing (and probably Expanded). "Pair kerning" is selected by default.
Kerning = adjusting (usually reducing) the space between two letters so they don't appear oddly space, as in the case of A and V.
Tracking = adjusting (usually increasing) the space between letters in a line or even a word or two, usually to get rid of wide gaps between words that can't be fixed by hyphenating.
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