I dunno your space requisites but I would use Dropbox to sync automatically everything... Install it on your pc. Point the dropbox folder to a NAS share. Install dropbox in your laptop locally. If space is a concern you may move the library database (not the books) to dropbox. Though I don't how to move only the database to a folder I've seen a description of how to achieve that in this same forum.
Khonshu
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