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Go into [Preferences] - [Email Delivery]
Add your email address to the top box by pressing the green plus-sign.
Then repeat you email address in the 'Send email from' box.
Save Preferences by pressing OK.
Go back to your library, select a book/news (presumably with a mobi format for your Kindle).
Press [Connect/share] button and choose one of the 'email to' options.
You should get a little pop-up balloon telling you that calibre has sent the email.
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