@Macondo: From what I can see for reports of the same error in other applications, there is something in the certificate, or something in the cacerts on your machine, that is causing the problem when read under Python 3. My suggestion for using the browser was to see if it worked elsewhere, and Microsoft's browsers can update the system certificates and stores if they are out of date.
There are several suggestions to fix this, but, there are some issues that I haven't sorted out yet.
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