Just did some searching, looks like some are already available:
1st volume:
http://www.amazon.com/exec/obidos/AS...?tag=sfsi0c-20
http://www.sfsignal.com/archives/201...ardner-dozois/
just bought volume 1 and 2 for $7.99 each at Amazon.
looks like it jumps to #15 after 2 though...so missing 3-14 ..
There is a listing of the contents of each volume here:
http://www.squidoo.com/the-years-best-science-fiction