http://manybooks.net/help/devices/nook.php
you aren't supposed to use ADE to get manybooks
.net books onthe nook, they are all DRM free.
Quote:
You can read manybooks eBooks on your nook by placing them in the "my stuff" folder using the USB connection to your computer. See the nook Tech Specs page for a list of nook-supported ePub, PDB and PDF files.
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what you did- downloading directly to the folder on your devcie as it was connected via USB as storage- is perfectly fine.