The strange path and the fact that you didn't see the welcome wizard makes me ask: is there any chance that you or someone using that name installed a previous version of calibre? It looks like calibre is trying to use a USB drive, which means it has been used on that computer before.
In any event, try the following:
1) log in as you, not admin
2) Using the file explorer, navigate to c:\users\[your user name]\AppData\Roaming
Unless you have changed the 'view hidden files' option, windows will complain about showing you this folder. Ignore the complaints.
3) You should see a folder named 'calibre'. To be sure it is the correct folder, check inside it for files global.py, gui.py, and gui.json, along with several other files.
4) Delete the calibre folder in its entirety.
5) Start calibre.
You should now get the welcome wizard.
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