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you can, if you want to use a program like ifunbox. with this program loaded up on your iphone itself you need no program on the PC. you can also drag and drop music into and out of your iphone without itunes, a feature other people find useful.
so in theory, you could visit a friend, he likes a song on your iphone, you just plug it in (assuming he has a cable) and copy the song off. no ifunbox needed. no itunes needed (which wouldn't copy off anyway).
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