I had an identical problem yesterday and spent an hour with sony support today to get it resolved. The good news is that it is resolved -- multiple steps, but done.
First, go to your <user>Library/Preferences/ and remove the folders called Sony Corporation; fsk; and Marlin
Then go to system preferences and choose language preferences. Choose US (computer) from the popup if US is the listed language -- why there is a difference is obscure, but apparently this is important to sony.
Then go to applications and delete the reader library app
reinstall reader library and launch.
This will reinstall without a reference to your downloaded books, so click on Library then go to the file menu and choose Import... Navigate to your library location - probably Documents/My Books/... select all the books you want referenced in your library and go from there.
Good luck.
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