My experience with PDF's on the iLiad:
On the iLiad PDF's work the fastest -- both in loading and navigating -- compared with other filetypes. And when properly formatted they also look the best.
I format all books(fiction) for my iLiad in OpenOffice, based on a custom template and then I export them to PDF.
When I just got my iLiad I loaded a few dozen PDF's on it, but some took ages (several minutes) to load. After a few resets I got so annoyed with those I decided to create everything with OpenOffice (which produces the fastest PDF's) and I've been a happy reader ever since.
Some of those bad PDF's I fixed. I remember they had to do with multiple images on one page (Baen-pdf's for example). So I removed those pages with Adobe to make them work.
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