Yes
You do this by opening up the book template and not a new document.
To open the template you need to navigate to the directory wher the Bookcreator.dot file is located. The right click on the file. You should see a list of options on how to open the file. Select the "Open" menu option.
Configure the page layout as you like save the document and CLOSE it out-- any changes made in the template file will apply to all documents you open with the template so make sure you save and close.
Now go and open a new document and your new settings should show up.
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