Depends. Are both devices registered with the application that downloaded the books or are they drm-free?
If they are DRM books they will need to go through the Library app - Sony and or Adobe Digital Editions and then load them onto the new reader once it is registered with the app.
If they are drm free you can just copy them to a directory and then plug in the new reader and copy to it...
Oh and welcome to mobileread!
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