Rhalb, are you using the Windows 7 beta, the RC (release candidate), or are you using the full release version (released a couple of weeks ago)? Also, did you upgrade directly from Vista, or did you do a clean install?
I'm using Win 7 x64 RC. I downloaded the latest version of ebook software from the Sony site last week (so it was the current one) and had never installed the previous version. It works fine for me, and it syncs perfectly with my PRS-600 with no problems. So, either we're not using the exact same version of the OS, or you've got some software/driver baggage in there mucking things up.
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