Hmm, I'm at a loss. The Console output indicates that the launched executable is /Applications/calibre.app/Contents/MacOS/python
However, the Info.plist file correctly specifies /Applications/calibre.app/Contents/MacOS/calibre as the executable that should be launched. So I have no idea why Launch Services is launching python instead of calibre.
Try renaming /Applications/calibre.app/Contents/MacOS/python to /Applications/calibre.app/Contents/MacOS/python.disable
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