In windows XP, when you right-click on a folder and select Properties, a new window appear. In this window you have a "share" tab. In this tab you can let the folder be shared by everyone on the network. What itimpi was saying is that if you do that on your library directory, all of your other computer will have access to this folder. So they could point Calibre to this shared folder. So everyone will be using the same file and do their modification on the same database.
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