The 0.5.x series of Calibre also needed python 2.6 so reverting to that Calibre release will not solve your problem.
What problem are you having using the 0.6.0 version? Some people have reported not having the libphonon.so.4 library in their linux distribution which is required by the 0.6.0 binary install of Calibre. Installing this package seems to have solved the problem for most people although those running 64-bit versions of linux seem to sometimes have issues about getting the 32-bit version installed.
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