For big books, it'd probably be worth exporting them from Calibre to disk, then using the Sony eBook Library to load them & thus have it to pre-paginate them. I don't bother myself, but I suspect that I read shorter books, as I don't recall having to wait anything like that sort of duration.
Another option might be to convert them to ePub rather than LRF, if that's feasible, as that doesn't have the same startup issues, although that brings it's own set of compromises...
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