I had to shut everything down, then connect my reader, then open Adobe DE to authorise my reader.
If you can do that, I would then shut everything down before opening up calibre (you shouldn't need to, but it might help). Then you need to find the book where ADE has saved it, not where you originally saved it when you downloaded it, to import the book into calibre.
However, if you are having problems with calibre, if you can get ADE to recognise your reader, it will appear as a shelf in ADE and you can move the book onto your reader there instead of using calibre. It might help you get started reading the book quicker!
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