I assume you've copied the calibre2web catalog files and your whole calibre library to CalibreBooks? Do you have the _CATALOGS folder inside the CalibreBooks folder?
If yes, the correct address should be:
32.147.152.166:54343/CalibreBooks/_CATALOGS/catalog.xml
...I think. Haven't tried the latest Calibre2Web version but that's what I have with v0.3.
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