EDIT: Sorry. I answered the wrong question here. The OP wants to change the styling of the TOC panel in the Viewer. I mistakenly thought he wanted to change the styling of the actual TOC in the book.
ORIGINAL:It might be possible by editing inline_toc_styles.css. I'm not sure where yours might be but in Bazzite with a flatpak version of Calibre, mine is in /home/dave/.var/app/com.calibre_ebook.calibre/config/calibre/resources/templates/.
I'd assume some file path ending in calibre/resources/templates.
It looks like Calibre just sticks whatever it finds in that file at the top of the TOC page.
EDIT: According to
https://www.mobileread.com/forums/sh...56&postcount=3
the path is:
AppData\Roaming\calibre\resources\templates\inline _toc_styles.css