That's just weird something is trying to load libxml.so.2 but nothing in calibre links against that. Maybe one of your calibre plugins? Try running it as
calibre-debug -g -- --ignore-plugins
In any case the workaround is simple just do
ln -s libxml2.so.16 /opt/calibre/lib/libxml2.so.2
that will force whatever it is to load libxml2.so.16
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