The user indeed does not have access to customize the Prettify option, but if you would like to prepare your own version of Sigil and you have a lot of time then you can fight and modify this option or even create a new one to suit your needs.
However, if someone would like to play around, the relevant functions can be found in
this file.
Sample XHTML file before:
Sample XHTML file after:
Only for those interested in my changes (it can be optimized, but I leave it that way for code readability):