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How do I make it start directly on KOReader?
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On device restart?

You can't do that at all. KOL is just a "booklet" = special item listed amongst books in Library. You start KOReader by
manually opening that "book".
So instead having to do "open KUAL > open KOReader submenu inside KUAL > choose 1 of 3 available options/command" you just open KOL and that stars KOReader.
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KPPMainAppV2...., KPPMainAppV2....
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Those are stupid crash logs and dump data files from Kindle's homescreen UI app and you should just delete them.