Sync to what? Amazon only syncs to other Amazon. An app on phone or PC isn't much use really if you are reading on ereader and wanting your annotations for some purpose/
The most useful thing is EXPORT of highlights & annotations, also setting ebook metadata. Kobo does that better than Amazon.
I've had Kobo & Amazon. I've multiple devices I manage with Calibre. I personally find no value in Sync compared to export.
The Scribe is a very walled garden and MTP, so more locked to Amazon than other Kindles. Amazon has a tendency to accidentally delete sideloaded content.
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