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When you open Control Panel => Autoplay, what does it show? If there is a checkmark in Use Autoplay for all media and devices remove it, then go down the list of media, software and devices and set all the action boxes to take no action.
Then plugin your monitor and see if it opens calibre. If it doesn't, you can try re-enabling autoplay options if you want to. If it does, then check if a new device shows under devices and set it to take no action.
Otherwise, it's not an Autoplay action and it'll likely be real fun to track down.
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