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/Users/thomas/Library/CloudStorage/OneDrive-Personal/c
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Never use a NAS, network share (Samba or real MS windows or other), Google, One Drive, Dropbox or any other Internet service for a running library. Those are only for sharing a copy of your local files (not direct access by an application).
Exclude all so called "cloud" services (some distant server that belongs to someone else) from any folders/directories used by programs like calibre. It will break many things. This has always been true, not just for calibre. Even if it has worked, it will break.