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Save docx, not doc. They are quite different!
Also the paragraph styles need to be created /set, that won't be automatic, between 1 and 2. Calibre creates the CSS from the style set for a paragraph (includes headings, basically ANY text terminated by <enter key>). The HTML is based on the content of the paragraph/heading.
Also a true ebook can't have a background! It won't work on most ereaders or apps, even if it can be got to work in a desktop preview!
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