@Hightree: Depending no your use-cases, playing with the ZSH profile/env in /mnt/us/usbnet/etc/zsh might be enough to fake it.
But if you were hoping to use it for scp/sftp, that won't quite work, because ZSH isn't the default shell.
I honestly don't recall what's persistent and what's dynamic, but assuming none of that is dynamic, you might have better luck just creating a new dedicated user that lives wherever you want it.
(I wouldn't necessarily recommend touching the state of the root account, because you never really know what that might break in fun and interesting ways...).
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