Use Export then Import rather than trying to copy the library files and settings.
I think Calibre for Linux, Mac and Windows are the same functionality apart from some plug-ins that are really kind of "wrappers" to Windows programs. I moved from Windows to Linux.
Don't store the Calibre Library on Cloud or Network storage, only on a local drive (SATA, IDE, USB, SCSI are local) and not on FAT32 or exFAT formatted storage.
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