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I had this error message to0, but my circumstances are different and it was my foolish mistake. It's been a while since I had set up a new library folder in Calibre. In the create-library window I simply typed in the new library name and clicked on OK resulting in "Windows error 5: Access is denied" because it was trying to access a location on my C drive. The problem goes away if I simply click on the icon to the right of the new library name and select the location on my other drive where I the other Calibre library folders are located.
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