@theducks - I'm confused, the ondevice/On device column is set by the Send to Device tool - e.g. a Kobo, Kindle, Nook etc.
But the OP refers to Save to Disk, i.e. save book to a file system location - e.g. C:\Users\fred\SavedBooks.
@jsibley - can you confirm whether you're asking about the Save to Disk tool or the Send to Device tool.
If it's Save to Disk the answer is no. You could set a Yes/No custom column manually when you do the save, which you might be able to automate with the Action Chain plugin.
BR
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