A separate file causes a page break. It's the most reliable way to do page breaks. It's implicit, no command needed.
But I think a single file (implies no page breaks) or a single page long PDF is so stupid I won't even try my earlier suggestion.
The big advantage of real ebooks and regular printed paper books is pages. The Web using a single page per file is a broken concept, more than 2000 years out of date. Which is why I might paste one or more web sites into LO Writer (or previously MS Word) , fix formating, extra Save As in Docx and make an epub.
I'm 100% confident of two things:
1) I know multiple ways to achieve what you want. it's probably easy.
2) I never would even try it for research.
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