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Also even if you could, it won't work. Titles can easily have characters illegal in file names (varies with OS and filesytem in use).
As DNSB says, pretend the Calibre files don't exist. They only exist at all because it's never worked well for any database to import that sort of thing inside a database.
That's why there is an Export to Disk File command and also why Calibre creates a copy of any file imported (as if it was really inside a database).
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