Definitely do not recommend writing in Sigil... although it is technically possible. There are other software suites out there designed to organize and otherwise help an author keep focused on writing.
L.O. will work just fine. Just make sure you setup your styles...and here is the important part.... USE THEM consistently! (there are a few good threads here on MR that can point out how to use styles properly)
Then you can import the resulting html file into Sigil to do your final cleanup and ePubify it....
Cheers!
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