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ps: It is even easier if you open a macOS Finder window and select your home folder. Then go to Finder's View menu item in the top menubar and select "Show View Options" and then check the box beside "Show Library Folder".
This will "unhide" your local Library Folder and you can then easily navigate using Sigil's File->Open menu to select your Home folder and then "Library" then "Mobile Documents" and com~apple~CloudDocs folder just like any other folder.
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