Speaking of smallcaps. I am not a fan of them to start the chapters/section break.
If you use a font that has small caps in it and the program that's displaying the eBook supports font-variant: small-caps; then all is good as the small caps will look good and not simulated.
But most books don't use small caps too much so simulated is easy enough to ignore. As to the size, I use 0.8333em. I don't know if that's the correct size or not, but it looks good enough to me.
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