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No, doc is poor, export (Save As) an extra copy as docx
It's also easier to convert docx to epub in Calibre. Sigil is better for experts handcrafting an ebook. It's not needed for this and the styles, formatting & centring should always be done in the wordprocessor, not in Sigil or Calibre, unless you only have an ebook and no wordprocessor source,
Properly done styles editing an odt with an extra docx "Save As" will automatically create that sort of HTML and CSS.
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