That won't work because you haven't told it what to do. You just typed in a path. You seem to be getting them wrong each time, or mixing them up.
Choose one method or the other
Copy and paste this...
"%PROGRAMFILES(x86)%"\Calibre2\calibre-debug.exe -g
OR
copy and paste this
cd C:\Program Files (x86)\Calibre2
calibre-debug.exe -g
This one is two separate commands. Do the first one and then the second one.
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