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Other alternatives:
"Print" on the Calibre Viewer works well to create a PDF file. It only creates a PDF and can add page numbers.
Best option is format and page size, header, footer, page numbers, contents with page numbers etc in LO Writer and Export a PDF. Better than most versions of Word for PDF creation and free. Gives publisher quality PDF assuming the page format, headers, footers, styles, image resolutions etc are OK. There is even an option on export to resample all images to 300 dpi (or other desired resolution).
Since you HAVE a docx, I'd only use Calibre to make an epub, and then convert epub to mobi, azw3, kfx, kepub, lrf, pdb (both sorts), not a PDF.
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