With some rare exceptions you can read any purchased book on any Kindle app or device registered to your Amazon account. On your Paperwhite you should be able to see the new book listed under YOUR LIBRARY as long as you select the category ALL instead of DOWNLOADED.
Another way is to click Search and start typing the title of the book. Once you see a book icon with the full title click to download it.
If for some reason that book isn't available on your Kindle you can always return it for a refund.
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