Problem solved. Books.db turned out to be the calibre.db after all. It was set a long time ago with CALIBRE_OVERRIDE_DATABASE_PATH. I removed the override and copied and renamed books.db to the NAS-folder. Now I can use Calibre on both PC's, even at the same time. With the Calibre webclient I can only see book title and author. All other meta seems hidden. Then I have to download it, while I want to use the book on its location on the NAS so highlights etc are preserved. Unfortunately this seems not possible while using FBReader on my phone.
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