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ePub.
A PDF is a sort of envelope, it might not actually have text. It's really either a facsimile of a paper document or an electronic proof to create one.
Calibre on the Mac to organise, edit, convert and export ebooks. I export badly formatted ones as RTF and then fix styles and headings in LO Writer using native odt format. I save an extra copy in docx for Calibre to make an epub. I make other formats from the epub.
The Calibre ebook reading app is also good. Should be able to work with Text to Speech.
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