Reading List doesn't assign any keyboard shortcuts to actual keys--it just makes them available for you to assign as you see fit.
Calibre, by default, appears to assigns Shift-V to 'Continue reading previous book'. You may need to unassign it (by changing that to a 'Custom' key setting) before you can re-assign it.
Also, in Reading List config, under the 'Other' tab, there's a button for 'Keyboard Shortcuts' that will take you directly to RL's shortcuts.
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